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Ligand-Controlled Regioselective Hydrocarboxylation of Styrenes
with CO2 by Combining Visible Light and Nickel Catalysis

Meng, Qing-Yuan , Wang, Shun, Huff, Gregory S. and König, Burkhard (2018) Ligand-Controlled Regioselective Hydrocarboxylation of Styrenes
with CO2 by Combining Visible Light and Nickel Catalysis.
Journal of the American Chemical Society 140, pp. 3198-3201.

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Abstract

The ligand-controlled Markovnikov and anti-Markovnikov hydrocarboxylation of styrenes with atmospheric pressure of CO2 at room temperature using dual visible-light-nickel catalysis has been developed. In the presence of neocuproine as ligand, the Markovnikov product is obtained exclusively, while employing 1,4-bis(diphenylphosphino)butane (dppb) as the ligand favors the formation of the ...

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Item type:Article
Date:2018
Institutions:Chemistry and Pharmacy > Institut für Organische Chemie > Lehrstuhl Prof. Dr. Burkhard König
Projects:GRK 1626 Chemische Photokatalyse
Identification Number:
ValueType
10.1021/jacs.7b13448DOI
Keywords:Hydrocarboxylation; Visible light catalysis
Dewey Decimal Classification:500 Science > 540 Chemistry & allied sciences
Status:Published
Refereed:Yes, this version has been refereed
Created at the University of Regensburg:Yes
Item ID:36825
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