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Ligand-Controlled Regioselective Hydrocarboxylation of Styrenes
with CO2 by Combining Visible Light and Nickel Catalysis

Meng, Qing-Yuan ; Wang, Shun ; Huff, Gregory S. ; König, Burkhard


The ligand-controlled Markovnikov and anti-Markovnikov hydrocarboxylation of styrenes with atmospheric pressure of CO2 at room temperature using dual visible-light-nickel catalysis has been developed. In the presence of neocuproine as ligand, the Markovnikov product is obtained exclusively, while employing 1,4-bis(diphenylphosphino)butane (dppb) as the ligand favors the formation of the ...


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