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Effect of Penta-arylated Cp Ligands on Synthesis and Reactivity of Transition Metal Eₙ (E = P, As) Ligand Complexes

Modl, Moritz (2019) Effect of Penta-arylated Cp Ligands on Synthesis and Reactivity of Transition Metal Eₙ (E = P, As) Ligand Complexes. PhD, Universität Regensburg.

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Date of publication of this fulltext: 20 May 2019 04:58

Abstract (English)

Until now, numerous Eₙ (E = P, As) ligand complexes of transition metals are reported, containing different ligand systems. However, examples with sterically highly demanding Cpᴿ ligands and perarylated cyclopentadienyl ligands in particular, are rather rare. They are restricted to compounds of manganese, iron and cobalt due to the lack of appropriate precursors for the preparation. The ...

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Translation of the abstract (German)

Bis heute sind zahlreiche Eₙ-Ligandkomplexe (E = P, As) der Übergangsmetalle mit verschiedenen Ligandsystemen bekannt. Jedoch sind Beispiele mit sterisch sehr anspruchvolle Cpᴿ-Liganden und insbesondere mit perarylierten Cyclopentadienylliganden selten. Diese sind auf Verbindungen des Mangans, Eisens und Cobalts beschränkt, da es an geeigneten Vorstufen für die Synthese mangelt. Zu diesem Zweck ...

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Item type:Thesis of the University of Regensburg (PhD)
Date:20 May 2019
Referee:Prof. Dr. Manfred Scheer
Date of exam:18 May 2018
Institutions:Chemistry and Pharmacy > Institut für Anorganische Chemie > Chair Prof. Dr. Manfred Scheer
Keywords:Cyclopentadienyl, Phosphor, Arsen, Übergangsmetall
Dewey Decimal Classification:500 Science > 540 Chemistry & allied sciences
Status:Published
Refereed:Yes, this version has been refereed
Created at the University of Regensburg:Yes
Item ID:37409
Owner only: item control page

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