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NMR Spectroscopic Investigations on Asymmetric Aminocatalysis

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Seegerer, Andreas
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Date of publication of this fulltext: 26 Jun 2019 05:52

Abstract (English)

In this thesis, the main focus of interest was the generation of an improved understanding about reaction mechanisms in modern organic chemistry by NMR spectroscopy. For the first time, several mechanistic questions in asymmetric aminocatalysis, including enamine and dienamine catalysis were answered by using a powerful combination of new tools and techniques (CEST, RDS-shift) with ...


Translation of the abstract (German)

Im Fokus dieser Arbeit lag allem voran die Verbesserung des Verständnisses für Reaktionsmechanismen in der modernen organischen Chemie mittels NMR Spektroskopie. Hierbei, konnte zum ersten Mal eine Vielzahl von mechanistischen Fragestellungen in der asymmetrischen Aminokatalyse, inklusive Enamine- und Dienamine-Katalyse, durch die Kombination von neuen Instrumenten und Techniken (CEST, RDS-shift) ...


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