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Photocatalytic Barbier Reaction – Visible-Light induced Allylation
and Benzylation of Aldehydes and Ketones

Berger, Anna Lucia, Donabauer, Karsten and König, Burkhard (2018) Photocatalytic Barbier Reaction – Visible-Light induced Allylation
and Benzylation of Aldehydes and Ketones.
Chemical Science.

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Date of publication of this fulltext: 06 Aug 2018 13:01

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Abstract

We report a photocatalytic version of the Barbier type reaction using readily available allyl or benzyl bromides and aromatic aldehydes or ketones as starting materials to generate allylic or benzylic alcohols. The reaction proceeds at room temperature under visible light irradiation with the organic dye 3,7-di(4-biphenyl)1-naphthalene-10-phenoxazine as a photocatalyst and DIPEA as sacrificial ...

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Item type:Article
Date:2018
Institutions:Chemistry and Pharmacy > Institut für Organische Chemie > Lehrstuhl Prof. Dr. Burkhard König
Projects:GRK 1626 Chemische Photokatalyse
Identification Number:
ValueType
10.1039/C8SC02038HDOI
Keywords:Photocatalysis; Barbier-type reaction; organic photocatalyst
Dewey Decimal Classification:500 Science > 540 Chemistry & allied sciences
Status:Published
Refereed:Yes, this version has been refereed
Created at the University of Regensburg:Yes
Item ID:37585
Owner only: item control page

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