Ammoniates of Zintl phases: Similarities and differences of binary phases A4E4 and their corresponding solvates

URN to cite this document:: urn:nbn:de:bvb:355-epub-376159
DOI to cite this document:: 10.5283/epub.37615

Lorenz, Corinna

; Gärtner, Stefanie

; Korber, Nikolaus

License: Creative Commons Attribution 4.0
PDF - Published Version
(3MB)

Date of publication of this fulltext: 29 Aug 2018 13:16

Alternative links to fulltext:DOI

Details

Preview

Indexed in

Export bibliographical data

Abstract

The combination of electropositive alkali metals A (A = Na-Cs) and group 14 elements E (E = Si-Pb) in a stoichiometric ratio of 1:1 in solid state reactions results in the formation of polyanionic salts, which belong to a class of intermetallics for which the term Zintl compounds is used. Crystal structure analysis of these intermetallic phases proved the presence of tetrahedral tetrelide ...