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Ammoniates of Zintl phases: Similarities and differences of binary phases A4E4 and their corresponding solvates

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Lorenz, Corinna ; Gärtner, Stefanie ; Korber, Nikolaus
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Date of publication of this fulltext: 29 Aug 2018 13:16


The combination of electropositive alkali metals A (A = Na-Cs) and group 14 elements E (E = Si-Pb) in a stoichiometric ratio of 1:1 in solid state reactions results in the formation of polyanionic salts, which belong to a class of intermetallics for which the term Zintl compounds is used. Crystal structure analysis of these intermetallic phases proved the presence of tetrahedral tetrelide ...


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