Molecular Structures of Enantiomerically-Pure (S)-2-(Triphenylsilyl)- and (S)-2-(Methyldiphenylsilyl)pyrrolidinium Salts

URN to cite this document:: urn:nbn:de:bvb:355-epub-376232
DOI to cite this document:: 10.5283/epub.37623

Bauer, Jonathan O. ; Strohmann, Carsten

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Date of publication of this fulltext: 29 Aug 2018 11:48

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Abstract

Silyl-substituted pyrrolidines have gained increased interest for the design of new catalyst scaffolds. The molecular structures of four enantiomerically-pure 2-silylpyrrolidinium salts are reported. The perchlorate salts of (S)-2-(triphenylsilyl)pyrrolidine [(S)-1·HClO4] and (S)-2-(methyldiphenylsilyl)pyrrolidine [(S)-2·HClO4], the trifluoroacetate (S)-2·TFA, and the methanol-including ...