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Structural Chemistry of Halide including Thallides A8Tl11X1−n (A = K, Rb, Cs; X = Cl, Br; n = 0.1–0.9)

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Gärtner, Stefanie ; Tiefenthaler, Susanne ; Korber, Nikolaus ; Stempfhuber, Sabine ; Hischa, Birgit
Date of publication of this fulltext: 24 Aug 2018 11:16


A(8)Tl(11) (A = alkali metal) compounds have been known since the investigations of Corbett et al. in 1995 and are still a matter of current discussions as the compound includes one extra electron referred to the charge of the Tl-11(7-) cluster. Attempts to substitute this additional electron by incorporation of a halide atom succeeded in the preparation of single crystals for the lightest triel ...


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