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The Structure of [HSi9]3− in the Solid State and Its Unexpected Highly Dynamic Behavior in Solution

Lorenz, Corinna , Hastreiter, Florian, Hioe, Johnny, Nanjundappa, Lokesh , Gärtner, Stefanie , Korber, Nikolaus and Gschwind, R. M. (2018) The Structure of [HSi9]3− in the Solid State and Its Unexpected Highly Dynamic Behavior in Solution. Angewandte Chemie International Edition 57, pp. 12956-12960.

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Other URL: http://doi.org/10.1002/anie.201807080


Abstract

We report on the first unambiguous detection of the elusive [HSi9]3− anion in solutions of liquid ammonia by various 29Si and 1H NMR experiments including chemical exchange saturation transfer (CEST). The characteristic multiplicity patterns of both the 29Si and 1H resonances together with CEST and a partially reduced 1H,29Si coupling constant indicate the presence of a highly dynamic Si8 entity ...

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Item type:Article
Date:2018
Institutions:Chemistry and Pharmacy > Institut für Anorganische Chemie > Arbeitskreis Prof. Dr. Nikolaus Korber
Chemistry and Pharmacy > Institut für Organische Chemie > Arbeitskreis Prof. Dr. Ruth Gschwind
Identification Number:
ValueType
10.1002/anie.201807080DOI
Dewey Decimal Classification:500 Science > 540 Chemistry & allied sciences
Status:Published
Refereed:Yes, this version has been refereed
Created at the University of Regensburg:Yes
Item ID:37669
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