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The Structure of [HSi9]3− in the Solid State and Its Unexpected Highly Dynamic Behavior in Solution

Lorenz, Corinna ; Hastreiter, Florian ; Hioe, Johnny ; Nanjundappa, Lokesh ; Gärtner, Stefanie ; Korber, Nikolaus ; Gschwind, R. M.


We report on the first unambiguous detection of the elusive [HSi9](3-) anion in solutions of liquid ammonia by various Si-29 and H-1 NMR experiments including chemical exchange saturation transfer (CEST). The characteristic multiplicity patterns of both the Si-29 and H-1 resonances together with CEST and a partially reduced H-1,Si-29 coupling constant indicate the presence of a highly dynamic ...


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