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Contributions to the Chemistry of Phosphanylboranes

URN to cite this document:
urn:nbn:de:bvb:355-epub-377062
Hegen, Oliver Niklas
Date of publication of this fulltext: 28 Aug 2019 07:57


Abstract (English)

The primary object of this dissertation was the synthesis of new, monomeric or rather dimeric compounds consisting of the elements boron, as group 13 atom, and different pnictogens (phosphorus, arsenic, antimony), stabilized by a lewis base. By substitution of the weak lewis base (LB) SMe2 in the synthesized lewis acid/LB stabilized phosphanylborane (OC)5W-PH2BH2-SMe2 with different ...

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Translation of the abstract (German)

Ziel dieser Dissertation war u. a. die Darstellung neuer, monomerer bzw. dimerer Verbindungen aus den Elementen Bor, als Gruppe 13 Atom, und verschiedenen Pnictogenen (Phosphor, Arsen, Antimon), stabilisiert durch eine Lewis-Base. Durch Verdrängung der schwachen Lewis-Base (LB) SMe2 des dargestellten Lewis-Säure-Lewis-Base stabilisierten Phosphanylboranes (OC)5W-PH2BH2-SMe2 mittels verschiedener ...

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