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PPh4Cl in aqueous solution – the aggregation behavior of an antagonistic salt

Winkler, Robert, Buchecker, Thomas , Touraud, Didier and Kunz, Werner (2017) PPh4Cl in aqueous solution – the aggregation behavior of an antagonistic salt. Physical Chemistry Chemical Physics 19 (37), pp. 25463-25470.

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Abstract

The authors consider the antagonistic salt PPh4Cl as a hydrotrope. Surface tension measurements and solubilization expts. on a hydrophobic dye confirm the solubilization behavior of PPh4Cl, which is in-​between the one of SDS and SXS. With the help of scattering techniques (DLS, SLS, SAXS)​, NMR and cond. measurements, we show that in contrast to SDS as a hydrotrope with an inherent CMC, PPh4Cl ...

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Item type:Article
Date:2017
Institutions:Chemistry and Pharmacy > Institut für Anorganische Chemie > Chair Prof. Dr. Arno Pfitzner
Chemistry and Pharmacy > Institut für Organische Chemie > Arbeitskreis Prof. Dr. Ruth Gschwind
Chemistry and Pharmacy > Institut für Physikalische und Theoretische Chemie > Chair of Chemistry VI - Physical Chemistry (Solution Chemistry) > Prof. Dr. Werner Kunz
Identification Number:
ValueType
10.1039/C7CP02677CDOI
Keywords:aggregation phenylphosphine chloride solubilization soly
Dewey Decimal Classification:500 Science > 540 Chemistry & allied sciences
Status:Published
Refereed:Yes, this version has been refereed
Created at the University of Regensburg:Yes
Item ID:37726
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