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Visible Light Mediated Liberation and in situ Conversion of Fluorophosgene

Petzold, Daniel ; Nitschke, Philipp ; Brandl, Fabian ; Scheidler, Veronica ; Dick, Bernhard ; Gschwind, Ruth M. ; König, Burkhard



Abstract

The first example for the photocatalytic generation of a highly electrophilic intermediate that is not based on radical reactivity is reported. The single-electron reduction of bench-stable and commercially available 4-(trifluoromethoxy)benzonitrile by an organic photosensitizer leads to its fragmentation into fluorophosgene and benzonitrile. The in situ generated fluorophosgene was used for the ...

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