Go to content
UR Home

Synthesis of aryl sulfides via radical–radical cross coupling of electron-rich arenes using visible light photoredox catalysis

URN to cite this document:
DOI to cite this document:
Das, Amrita ; Maity, Mitasree ; Malcherek, Simon ; König, Burkhard ; Rehbein, Julia
[img]License: Creative Commons Attribution 4.0
PDF - Published Version
Date of publication of this fulltext: 10 Oct 2018 08:18


Electron-rich arenes react with aryl and alkyl disulfides in the presence of catalytic amounts of [Ir(dF(CF3)ppy)(2)(dtbpy)]PF6 and (NH4)(2)S2O8 under blue light irradiation to yield arylthiols. The reaction proceeds at room temperature and avoids the use of prefunctionalized arenes. Experimental evidence suggests a radical-radical cross coupling mechanism.

Owner only: item control page
  1. Homepage UR

University Library

Publication Server


Publishing: oa@ur.de
0941 943 -4239 or -69394

Dissertations: dissertationen@ur.de
0941 943 -3904

Research data: datahub@ur.de
0941 943 -5707

Contact persons