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Microglobule formation and a microscopic order parameter monitoring the phase transition of aqueous poly(N-isopropylacrylamide) solution

Yanase, K., Buchner, Richard and Sato, T. (2018) Microglobule formation and a microscopic order parameter monitoring the phase transition of aqueous poly(N-isopropylacrylamide) solution. Phys. Rev. Materials 2, 085601.

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Date of publication of this fulltext: 22 Nov 2018 09:53

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Other URL: https://journals.aps.org/prmaterials/abstract/10.1103/PhysRevMaterials.2.085601


Abstract

The coil-to-globule transition of poly(N-isopropylacrylamide) (pNIPAm) in water is generally believed to be driven by hydrophobic interaction between the isopropyl groups of its side chains. However, it is still unclear how dehydration and critical fluctuations of the polymer chains are correlated. Here, we use small- and wide-angle x-ray scattering and dielectric relaxation spectroscopy to cover ...

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Item type:Article
Date:2018
Institutions:Chemistry and Pharmacy > Institut für Physikalische und Theoretische Chemie > Chair of Chemistry VI - Physical Chemistry (Solution Chemistry) > PD Dr. Richard Buchner
Identification Number:
ValueType
10.1103/PhysRevMaterials.2.085601DOI
Dewey Decimal Classification:500 Science > 540 Chemistry & allied sciences
Status:Published
Refereed:Yes, this version has been refereed
Created at the University of Regensburg:Yes
Item ID:38040
Owner only: item control page

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