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[Co@Sn6 Sb6 ]3− : An Off-Center Endohedral 12-Vertex Cluster

Wilson, R. J., Hastreiter, Florian, Reiter, K., Büschelberger, Philipp, Wolf, Robert, Gschwind, Ruth M. , Weigend, F. and Dehnen, S. (2018) [Co@Sn6 Sb6 ]3− : An Off-Center Endohedral 12-Vertex Cluster. Angewandte Chemie International Edition 57 (47), pp. 15359-15363.

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Other URL: http://doi.org/10.1002/anie.201807180


We report on the asymmetric occupation of a 12‐vertex cluster centered by a single metal atom. Three salts of related intermetalloid cluster anions, [Co@Sn6Sb6]3− (1), [Co2@Sn5Sb7]3− (2), and [Ni2@Sn7Sb5]3− (3) were synthesized, which have pseudo‐C4v‐symmetric or pseudo‐D4h‐symmetric 12‐vertex Sn/Sb shells and interstitial Co− ions or Ni atoms. Anion 1 is a very unusual single‐metal‐“centered” ...


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Item type:Article
Institutions:Chemistry and Pharmacy > Institut für Anorganische Chemie > Arbeitskreis Prof. Dr. Robert Wolf
Chemistry and Pharmacy > Institut für Organische Chemie > Arbeitskreis Prof. Dr. Ruth Gschwind
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Dewey Decimal Classification:500 Science > 540 Chemistry & allied sciences
Refereed:Yes, this version has been refereed
Created at the University of Regensburg:Yes
Item ID:38141
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