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[Co@Sn6 Sb6 ]3− : An Off-Center Endohedral 12-Vertex Cluster

Wilson, R. J. ; Hastreiter, Florian ; Reiter, K. ; Büschelberger, Philipp ; Wolf, Robert ; Gschwind, Ruth M. ; Weigend, F. ; Dehnen, S.



Abstract

We report on the asymmetric occupation of a 12-vertex cluster centered by a single metal atom. Three salts of related intermetalloid cluster anions, [Co@Sn6Sb6](3-) (1), [Co-2@Sn5Sb7](3-) (2), and [Ni-2@Sn7Sb5](3-) (3) were synthesized, which have pseudo-C-4v-symmetric or pseudo-D-4h-symmetric 12-vertex Sn/Sb shells and interstitial Co- ions or Ni atoms. Anion 1 is a very unusual ...

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