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Alkenylation of unactivated alkyl bromides through visible light photocatalysis

Zhou, Quan-Quan, Düsel, Simon J. S., Lu, Liang-Qiu, König, Burkhard and Xiao, Wen-Jing (2019) Alkenylation of unactivated alkyl bromides through visible light photocatalysis. Chemical Communications 55, pp. 107-110.

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Abstract

Two visible-light driven alkenylation reactions of unactivated alkyl bromides, which were enabled by the use of Ir(dF(CF3)ppy)2(dtbbpy)PF6 as the photocatalyst and (TMS)3SiH as the atom transfer reagent to activate the alkyl bromides, were described for the first time. These protocols can be used to produce a variety of alkenes from easily available feedstock with good reaction efficiency and ...

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Item type:Article
Date:2019
Institutions:Chemistry and Pharmacy > Institut für Organische Chemie > Lehrstuhl Prof. Dr. Burkhard König
Projects:GRK 1626 Chemische Photokatalyse
Identification Number:
ValueType
10.1039/c8cc08362bDOI
Keywords:visible light photocatalysis; alkenylation reactions
Dewey Decimal Classification:500 Science > 540 Chemistry & allied sciences
Status:Published
Refereed:Yes, this version has been refereed
Created at the University of Regensburg:Partially
Item ID:38155
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