The Triple-Decker Complex [Cp*Fe(µ,η5:η5-P5)Mo(CO)3] as a Building Block in Coordination Chemistry

URN to cite this document:: urn:nbn:de:bvb:355-epub-383076
DOI to cite this document:: 10.5283/epub.38307

Elsayed Moussa, Mehdi ; Welsch, Stefan ; Dütsch, Luis ; Piesch, Martin ; Reichl, Stephan ; Seidl, Michael ; Scheer, Manfred

Preview

License: Creative Commons Attribution 4.0
PDF
(3MB)

Date of publication of this fulltext: 06 Feb 2019 10:54

Alternative links to fulltext:DOI Publisher

Details

Preview

Indexed in

Export bibliographical data

Abstract

Although the triple-decker complex [Cp*Fe(mu,eta(5):eta(5)-P-5)Mo(CO)(3)] (2) was first reported 26 years ago, its reactivity has not yet been explored. Herein, we report a new high-yielding synthesis of 2 and the isolation of its new polymorph (2'). In addition, we study its reactivity towards Ag-I and Cu-I ions. The reaction of 2 with Ag[BF4] selectively produces the coordination compound ...