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The Triple-Decker Complex [Cp*Fe(µ,η5:η5-P5)Mo(CO)3] as a Building Block in Coordination Chemistry

Elsayed Moussa, Mehdi, Welsch, Stefan, Dütsch, Luis, Piesch, Martin, Reichl, Stephan, Seidl, Michael and Scheer, Manfred (2019) The Triple-Decker Complex [Cp*Fe(µ,η5:η5-P5)Mo(CO)3] as a Building Block in Coordination Chemistry. Molecules 24 (2), p. 325.

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Date of publication of this fulltext: 06 Feb 2019 10:54

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Other URL: http://doi.org/10.3390/molecules24020325


Abstract

Although the triple-decker complex [Cp*Fe(µ,η5:η5-P5)Mo(CO)3] (2) was first reported 26 years ago, its reactivity has not yet been explored. Herein, we report a new high-yielding synthesis of 2 and the isolation of its new polymorph (2’). In addition, we study its reactivity towards AgI and CuI ions. The reaction of 2 with Ag[BF4] selectively produces the coordination compound ...

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Item type:Article
Date:17 January 2019
Institutions:Chemistry and Pharmacy > Institut für Anorganische Chemie > Chair Prof. Dr. Manfred Scheer
Projects:Open Access Publizieren (DFG)
Identification Number:
ValueType
10.3390/molecules24020325DOI
Keywords:triple-decker; cyclo-P5; weakly coordinating; molybdenum; silver; copper
Dewey Decimal Classification:500 Science > 540 Chemistry & allied sciences
Status:Published
Refereed:Yes, this version has been refereed
Created at the University of Regensburg:Yes
Item ID:38307
Owner only: item control page

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