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The Triple-Decker Complex [Cp*Fe(µ,η5:η5-P5)Mo(CO)3] as a Building Block in Coordination Chemistry

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Elsayed Moussa, Mehdi ; Welsch, Stefan ; Dütsch, Luis ; Piesch, Martin ; Reichl, Stephan ; Seidl, Michael ; Scheer, Manfred
Date of publication of this fulltext: 06 Feb 2019 10:54


Although the triple-decker complex [Cp*Fe(mu,eta(5):eta(5)-P-5)Mo(CO)(3)] (2) was first reported 26 years ago, its reactivity has not yet been explored. Herein, we report a new high-yielding synthesis of 2 and the isolation of its new polymorph (2'). In addition, we study its reactivity towards Ag-I and Cu-I ions. The reaction of 2 with Ag[BF4] selectively produces the coordination compound ...


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