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Mapping orbital changes upon electron transfer with tunnelling microscopy on insulators

Patera, Laerte L. ; Queck, Fabian ; Scheuerer, Philipp ; Repp, Jascha



Abstract

Electron transfer plays a crucial part in many chemical reactions1,2, including photosynthesis, combustion and corrosion. But even though redox-state transitions change the electronic structure of the molecules involved, mapping these changes at the single-molecule level is challenging. Scanning tunnelling microscopy provides insights into the orbital structure3 of single molecules and their ...

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