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Reactivity of Lewis Base Stabilized Pnictogenylboranes Towards Transition Metal Complexes

URN to cite this document:
urn:nbn:de:bvb:355-epub-383901
DOI to cite this document:
10.5283/epub.38390
Braese, Jens
Date of publication of this fulltext: 10 Jan 2020 06:40


Abstract (English)

The reactivity of Lewis base stabilized pnictogenylboranes towards transition metal complexes has been investigated. Reaction of Lewis base stabilized phosphinoborane monomer tBuHPBH2NMe3 with catalytic amounts of bis(η5:η1-adamantylidenepentafulvene)titanium provide a convenient new route to polyphosphinoboranes [tBuPH-BH2]n. This method offers access to high molecular mass materials under ...

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Translation of the abstract (German)

Die Reaktivität von Lewis Base stabilisierten Pnictogenylboranen gegenüber Übergangsmetallkomplexen wurde untersucht.


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