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Decarboxylative hydrazination of unactivated carboxylic acids by cerium photocatalysis

Yatham, Veera Reddy, Bellotti, Peter and König, Burkhard (2019) Decarboxylative hydrazination of unactivated carboxylic acids by cerium photocatalysis. Chemical Communications 55, pp. 3489-3492.

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Abstract

We report the cerium photocatalyzed radical decarboxylative
hydrazination of carboxylic acids with di-tert-butylazodicarboxylate (DBAD). The operationally simple protocol provides rapid access to synthetically useful hydrazine derivatives and overcomes current scope limitations in the photoredox-catalyzed decarboxylation of carboxylic acids.


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Item type:Article
Date:2019
Institutions:Chemistry and Pharmacy > Institut für Organische Chemie > Lehrstuhl Prof. Dr. Burkhard König
Projects:ERC No. 741623, Elitenetzwerk Bayern Syncat
Identification Number:
ValueType
10.1039/c9cc00492kDOI
Keywords:Decarboxylation; Photocatalysis
Dewey Decimal Classification:500 Science > 540 Chemistry & allied sciences
Status:Published
Refereed:Yes, this version has been refereed
Created at the University of Regensburg:Yes
Item ID:38412
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