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Tuning the dimensionality of organometallic-organic hybrid polymers assembled from [Cp₂Mo₂(CO)₄(η²-P₂)], rigid bipyridyl linkers and Ag ions

Moussa, Medhi Elsayed, Peresypkina, Eugenia V., Virovets, Alexander V., Venus, Dominik, Balazs, Gabor and Scheer, Manfred (2018) Tuning the dimensionality of organometallic-organic hybrid polymers assembled from [Cp₂Mo₂(CO)₄(η²-P₂)], rigid bipyridyl linkers and Ag ions. CrystEngComm 20 (46), pp. 7417-7422.

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Abstract

The reactions of the P₂ ligand complex [Cp₂Mo₂(CO)₄(η²-P₂)] (Cp = C₅H₅, 1) with Ag[Al{OC(CF₃)₃}₄] (Ag[TEF]) in the presence of the rigid bipyridyl linkers 1,2-di(pyridin-4-yl)ethyne (3), 4,4′-bis(pyridin-4-ylethynyl)-1,1′-biphenyl (4) and 4,4′-bipyridine (5) possessing various lengths are studied. The reaction with the longer linkers (3 and 4) leads to the formation of the 1D ...

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Item type:Article
Date:10 November 2018
Additional Information (public):PDF zugänglich ab 10.11.19 (RSC-Embargofrist)
Institutions:Chemistry and Pharmacy > Institut für Anorganische Chemie > Chair Prof. Dr. Manfred Scheer
Identification Number:
ValueType
10.1039/C8CE01792ADOI
Dewey Decimal Classification:500 Science > 540 Chemistry & allied sciences
Status:Published
Refereed:Yes, this version has been refereed
Created at the University of Regensburg:Yes
Item ID:38425
Owner only: item control page

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