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Tuning the dimensionality of organometallic-organic hybrid polymers assembled from [Cp₂Mo₂(CO)₄(η²-P₂)], rigid bipyridyl linkers and Ag ions

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Moussa, Medhi Elsayed ; Peresypkina, Eugenia V. ; Virovets, Alexander V. ; Venus, Dominik ; Balazs, Gabor ; Scheer, Manfred
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Date of publication of this fulltext: 18 Mar 2019 12:23


The reactions of the P₂ ligand complex [Cp₂Mo₂(CO)₄(η²-P₂)] (Cp = C₅H₅, 1) with Ag[Al{OC(CF₃)₃}₄] (Ag[TEF]) in the presence of the rigid bipyridyl linkers 1,2-di(pyridin-4-yl)ethyne (3), 4,4′-bis(pyridin-4-ylethynyl)-1,1′-biphenyl (4) and 4,4′-bipyridine (5) possessing various lengths are studied. The reaction with the longer linkers (3 and 4) leads to the formation of the 1D ...


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