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Highly soluble Cu(I)-acetonitrile salts as building blocks for novel phosphorus-rich organometallic-inorganic compounds
Moussa, Medhi Elsayed, Piesch, Martin, Fleischmann, Martin, Schreiner, Andrea, Seidl, Michael and Scheer, Manfred (2018) Highly soluble Cu(I)-acetonitrile salts as building blocks for novel phosphorus-rich organometallic-inorganic compounds. Dalton Transactions 20 (47), pp. 16031-16035.Date of publication of this fulltext: 18 Mar 2019 13:00
Article
DOI to cite this document: 10.5283/epub.38440
Abstract
The synthesis of the air-stable and highly soluble Cu(I)-acetonitrile salts [Cu(CH3CN)3.5][FAl] (1) ([FAL] = FAl{OC(C6F10)(C6F5)}3) and [Cu(CH3CN)4][TEF] (2) ([TEF] = Al{OC(CF3)3}4) is presented. Compound 1 reacts with the organometallic polyphosphorus complexes [Cp2Mo2(CO)4(ƞ2-P2)] (A) and [(Cp*Fe(ƞ5-P5)] (B) and salt 2 reacts with B to form one new (3) and three unprecedented (4-6) ...
The synthesis of the air-stable and highly soluble Cu(I)-acetonitrile salts [Cu(CH3CN)3.5][FAl] (1) ([FAL] = FAl{OC(C6F10)(C6F5)}3) and [Cu(CH3CN)4][TEF] (2) ([TEF] = Al{OC(CF3)3}4) is presented. Compound 1 reacts with the organometallic polyphosphorus complexes [Cp2Mo2(CO)4(ƞ2-P2)] (A) and [(Cp*Fe(ƞ5-P5)] (B) and salt 2 reacts with B to form one new (3) and three unprecedented (4-6) phosphorus-rich Cu(I) dimers with the general formulas [Cu2(µ,ƞ1:ƞ1-A)2(ƞ2-A)2][FAl]2 (3), [Cu2(µ,ƞ1:ƞ1-A)2(ƞ1-CH3CN)4][FAl]2 (4), [Cu2(µ,ƞ1:ƞ1-B)2(ƞ1-CH3CN)4][FAl]2 (5) and [Cu2(µ,ƞ1:ƞ1-B)2(ƞ1-CH3CN)4][TEF]2 (6).
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| Item type | Article | ||||
| Journal or Publication Title | Dalton Transactions | ||||
| Publisher: | Royal Socienty of Chemistry | ||||
|---|---|---|---|---|---|
| Volume: | 20 | ||||
| Number of Issue or Book Chapter: | 47 | ||||
| Page Range: | pp. 16031-16035 | ||||
| Date | 12 October 2018 | ||||
| Additional Information (public) | PDF zugänglich ab 12.10.19 (RSC-Embargofrist) | ||||
| Institutions | Chemistry and Pharmacy > Institut für Anorganische Chemie > Chair Prof. Dr. Manfred Scheer | ||||
| Identification Number |
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| Dewey Decimal Classification | 500 Science > 540 Chemistry & allied sciences | ||||
| Status | Published | ||||
| Refereed | Yes, this version has been refereed | ||||
| Created at the University of Regensburg | Yes | ||||
| URN of the UB Regensburg | urn:nbn:de:bvb:355-epub-384407 | ||||
| Item ID | 38440 |
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