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Highly soluble Cu(I)-acetonitrile salts as building blocks for novel phosphorus-rich organometallic-inorganic compounds

Moussa, Medhi Elsayed, Piesch, Martin, Fleischmann, Martin, Schreiner, Andrea, Seidl, Michael and Scheer, Manfred (2018) Highly soluble Cu(I)-acetonitrile salts as building blocks for novel phosphorus-rich organometallic-inorganic compounds. Dalton Transactions 20 (47), pp. 16031-16035.

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Abstract

The synthesis of the air-stable and highly soluble Cu(I)-acetonitrile salts [Cu(CH3CN)3.5][FAl] (1) ([FAL] = FAl{OC(C6F10)(C6F5)}3) and [Cu(CH3CN)4][TEF] (2) ([TEF] = Al{OC(CF3)3}4) is presented. Compound 1 reacts with the organometallic polyphosphorus complexes [Cp2Mo2(CO)4(ƞ2-P2)] (A) and [(Cp*Fe(ƞ5-P5)] (B) and salt 2 reacts with B to form one new (3) and three unprecedented (4-6) ...

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Item type:Article
Date:12 October 2018
Additional Information (public):PDF zugänglich ab 12.10.19 (RSC-Embargofrist)
Institutions:Chemistry and Pharmacy > Institut für Anorganische Chemie > Chair Prof. Dr. Manfred Scheer
Identification Number:
ValueType
10.1039/C8DT03723JDOI
Dewey Decimal Classification:500 Science > 540 Chemistry & allied sciences
Status:Published
Refereed:Yes, this version has been refereed
Created at the University of Regensburg:Yes
Item ID:38440
Owner only: item control page

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