Highly soluble Cu(I)-acetonitrile salts as building blocks for novel phosphorus-rich organometallic-inorganic compounds

URN to cite this document:: urn:nbn:de:bvb:355-epub-384407
DOI to cite this document:: 10.5283/epub.38440

Moussa, Medhi Elsayed ; Piesch, Martin ; Fleischmann, Martin ; Schreiner, Andrea ; Seidl, Michael ; Scheer, Manfred

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Date of publication of this fulltext: 18 Mar 2019 13:00

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Abstract

The synthesis of the air-stable and highly soluble Cu(I)-acetonitrile salts [Cu(CH3CN)3.5][FAl] (1) ([FAL] = FAl{OC(C6F10)(C6F5)}3) and [Cu(CH3CN)4][TEF] (2) ([TEF] = Al{OC(CF3)3}4) is presented. Compound 1 reacts with the organometallic polyphosphorus complexes [Cp2Mo2(CO)4(ƞ2-P2)] (A) and [(Cp*Fe(ƞ5-P5)] (B) and salt 2 reacts with B to form one new (3) and three unprecedented (4-6) ...