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Discrete and polymeric organometallic‐organic hybrid materials based on the diphosphorus complex [Cp₂Mo₂(CO)₄(η²‐P₂)], Cu salts, and 2,2′‐bipyrimidine
Article
Moussa, Medhi Elsayed, Attenberger, Bianca, Seidl, Michael, Schreiner, Andrea and Scheer, Manfred (2017) Discrete and polymeric organometallic‐organic hybrid materials based on the diphosphorus complex [Cp₂Mo₂(CO)₄(η²‐P₂)], Cu salts, and 2,2′‐bipyrimidine. European Journal of Inorganic Chemistry 2017, pp. 5616-5620.DOI to cite this document: 10.5283/epub.38441
Abstract
The reaction of the diphosphorus complex [Cp2Mo2(CO)(4)((2)-P-2)] (1), with the Cu-I salts [Cu(CH3CN)(4)][BF4] or [Cu(CH3CN)(4)][PF6], and a mixture of [Cu(CH3CN)(4)][BF4] and CuCl in the presence of 2,2-bipyrimidine (2) is studied. Depending on the Cu-I salts used and the layering solvent involved in the crystallisation, a variety of novel coordination compounds are accessible in moderate to ...
The reaction of the diphosphorus complex [Cp2Mo2(CO)(4)((2)-P-2)] (1), with the Cu-I salts [Cu(CH3CN)(4)][BF4] or [Cu(CH3CN)(4)][PF6], and a mixture of [Cu(CH3CN)(4)][BF4] and CuCl in the presence of 2,2-bipyrimidine (2) is studied. Depending on the Cu-I salts used and the layering solvent involved in the crystallisation, a variety of novel coordination compounds are accessible in moderate to excellent yields (26-80%): the novel dicationic molecular organometallic-organic hybrid complexes [{Cp2Mo2(CO)(4)(mu(3),(1:2:2)-P-2)}(4)(mu(2),(1:1:1:1)-C8H6N4)Cu-2][BF4](2) (3) and [{Cp2Mo2(CO)(4)(mu(3),(1:2:2)-P-2)}(2){Cp2Mo2(CO)(4)(mu(3),(2:2:2)-P-2)}(2)(mu(2),(1:1:1:1)-C8H6N4)Cu-2][PF6](2) (4), the unique neutral 1D organometallic-organic hybrid polymer [{Cp2Mo2(CO)(4)(mu(4),(1:1:2:2)-P-2)}(2)(mu(2),(1:1:1:1)-C8N6N4)(CuCl)(2)](n) (5) and the unprecedented 2D organometallic-organic hybrid polymer [{Cp2Mo2(CO)(4)(mu(4),(1:1:2:2)-P-2)}(mu(2),(1:1:1:1)-C8H6N4){Cu-2(mu-Cl)}](2)[BF4](2n) (6).
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| Item type | Article | ||||
| Journal or Publication Title | European Journal of Inorganic Chemistry | ||||
| Publisher | Wiley | ||||
| Open Access Type | Due to SHERPA/RoMEO | ||||
| Place of Publication | WEINHEIM | ||||
| Volume | 2017 | ||||
| Page Range | pp. 5616-5620 | ||||
| Date | 20 December 2017 | ||||
| Date of publication | 18 Mar 2019 13:43 | ||||
| Institutions | Chemistry and Pharmacy > Institut für Anorganische Chemie > Chair Prof. Dr. Manfred Scheer | ||||
| Identification Number |
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| Keywords | ONE-DIMENSIONAL POLYMERS; FULLERENE TOPOLOGY; BUILDING-BLOCKS; COORDINATION; LIGAND; DICHLOROMETHANE; FRAMEWORKS; PENTAPHOSPHAFERROCENE; SUPRAMOLECULE; CONSTRUCTION; Diphosphorus complex; Neutral hybrid polymer; Copper(I); Coordination polymers | ||||
| Dewey Decimal Classification | 500 Science > 540 Chemistry & allied sciences | ||||
| Status | Published | ||||
| Refereed | Yes, this version has been refereed | ||||
| Created at the University of Regensburg | Yes | ||||
| URN of the UB Regensburg | urn:nbn:de:bvb:355-epub-384418 | ||||
| Item ID | 38441 |
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