Discrete and polymeric organometallic‐organic hybrid materials based on the diphosphorus complex [Cp₂Mo₂(CO)₄(η²‐P₂)], Cu salts, and 2,2′‐bipyrimidine

URN to cite this document:: urn:nbn:de:bvb:355-epub-384418
DOI to cite this document:: 10.5283/epub.38441

Moussa, Medhi Elsayed ; Attenberger, Bianca ; Seidl, Michael ; Schreiner, Andrea ; Scheer, Manfred

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Date of publication of this fulltext: 18 Mar 2019 13:43

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Abstract

The reaction of the diphosphorus complex [Cp2Mo2(CO)(4)((2)-P-2)] (1), with the Cu-I salts [Cu(CH3CN)(4)][BF4] or [Cu(CH3CN)(4)][PF6], and a mixture of [Cu(CH3CN)(4)][BF4] and CuCl in the presence of 2,2-bipyrimidine (2) is studied. Depending on the Cu-I salts used and the layering solvent involved in the crystallisation, a variety of novel coordination compounds are accessible in moderate to ...