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Discrete and polymeric organometallic‐organic hybrid materials based on the diphosphorus complex [Cp₂Mo₂(CO)₄(η²‐P₂)], Cu salts, and 2,2′‐bipyrimidine

Moussa, Medhi Elsayed, Attenberger, Bianca, Seidl, Michael, Schreiner, Andrea and Scheer, Manfred (2017) Discrete and polymeric organometallic‐organic hybrid materials based on the diphosphorus complex [Cp₂Mo₂(CO)₄(η²‐P₂)], Cu salts, and 2,2′‐bipyrimidine. European Journal of Inorganic Chemistry 2017, pp. 5616-5620.

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Abstract

The reaction of the diphosphorus complex [Cp2Mo2(CO)(4)((2)-P-2)] (1), with the Cu-I salts [Cu(CH3CN)(4)][BF4] or [Cu(CH3CN)(4)][PF6], and a mixture of [Cu(CH3CN)(4)][BF4] and CuCl in the presence of 2,2-bipyrimidine (2) is studied. Depending on the Cu-I salts used and the layering solvent involved in the crystallisation, a variety of novel coordination compounds are accessible in moderate to ...

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Item type:Article
Date:20 December 2017
Institutions:Chemistry and Pharmacy > Institut für Anorganische Chemie > Chair Prof. Dr. Manfred Scheer
Identification Number:
ValueType
10.1002/ejic.201701285DOI
Keywords:ONE-DIMENSIONAL POLYMERS; FULLERENE TOPOLOGY; BUILDING-BLOCKS; COORDINATION; LIGAND; DICHLOROMETHANE; FRAMEWORKS; PENTAPHOSPHAFERROCENE; SUPRAMOLECULE; CONSTRUCTION; Diphosphorus complex; Neutral hybrid polymer; Copper(I); Coordination polymers
Dewey Decimal Classification:500 Science > 540 Chemistry & allied sciences
Status:Published
Refereed:Yes, this version has been refereed
Created at the University of Regensburg:Yes
Item ID:38441
Owner only: item control page

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