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The Diphosphorus Complex [Cp₂Cr₂(CO)₄(η²‐P₂)] as a Building Block in the Coordination Chemistry of Silver

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Moussa, Medhi Elsayed ; Welsch, Stephan ; Gregoriades, Laurence John ; Balázs, Gábor ; Seidl, Michael ; Scheer, Manfred
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Date of publication of this fulltext: 18 Mar 2019 14:08


The reaction of the tetrahedral diphosphorus complex [Cp2Cr2(CO)(4)(eta(2)-P-2)] (Cp = C5H5) (2) with Ag[Al{OC(CF3)(3)}(4)] (AgTEF) (3) leads to the formation of the Ag-I dimer [Ag-2(eta(2)-2) (eta(1)-2)(eta(1):eta(1)-2)(2)][TEF](2) (5). This dimer can be used as a suitable precursor for the synthesis of the unprecedented 1D organometallic-organic hybrid polymer ...


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