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Oxidation of Substituted Phosphanylboranes with Chalcogens

Marquardt, Christian, Hegen, Oliver, Kahoun, Tobias and Scheer, Manfred (2017) Oxidation of Substituted Phosphanylboranes with Chalcogens. Chemistry - A European Journal 23 (18), pp. 4397-4404.

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Other URL: http://doi.org/10.1002/chem.201605625


Abstract

The elemental chalcogens sulfur, selenium, tellurium and bis(trimethylsilyl) peroxide as an oxygen source are applied for the oxidation of the phosphanylboranes Ph2P-BH2 center dot NMe3 (1) and tBuHP-BH2 center dot NMe3 (2). The corresponding monooxidation products Ph2P(X)-BH2 center dot NMe3 (X= O-Te, 3a-d) and tBuHP(X)-BH2 center dot NMe3 (X= O-Te, 4a-d) were obtained in good yields and ...

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Item type:Article
Date:2017
Institutions:Chemistry and Pharmacy > Institut für Anorganische Chemie > Chair Prof. Dr. Manfred Scheer
Identification Number:
ValueType
10.1002/chem.201605625DOI
Keywords:MAIN-GROUP ELEMENTS; PRIMARY PHOSPHINES; CONVENIENT ROUTE; REAGENTS; BORANES; CHAINS; boron; chalcogens; oxidation; phosphanylboranes; phosphorus
Dewey Decimal Classification:500 Science > 540 Chemistry & allied sciences
Status:Published
Refereed:Yes, this version has been refereed
Created at the University of Regensburg:Yes
Item ID:38584
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