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Visible-Light-Driven Aerobic Photooxidation of Aldehydes to Methyl Esters Catalyzed by Riboflavin Tetraacetate

Mühldorf, Bernd and Wolf, Robert (2017) Visible-Light-Driven Aerobic Photooxidation of Aldehydes to Methyl Esters Catalyzed by Riboflavin Tetraacetate. ChemCatChem 9 (6), pp. 920-923.

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Other URL: http://doi.org/10.1002/cctc.201601504


Abstract

Riboflavin tetraacetate (RFT) catalyzes the aerobic esterification of para-substituted benzaldehydes to their corresponding methyl esters. The reaction proceeds under visible-light irradiation in MeOH/MeCN in the presence of a Bronsted acid such as HCl. Electron transfer from the in situ formed dimethyl acetal to the photoexcited triplet flavin appears to be a key mechanistic step. The acid ...

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Item type:Article
Date:2017
Institutions:Chemistry and Pharmacy > Institut für Anorganische Chemie > Arbeitskreis Prof. Dr. Robert Wolf
Identification Number:
ValueType
10.1002/cctc.201601504DOI
Keywords:BENZYL ALCOHOL DERIVATIVES; ALPHA-KETO ACIDS; FACILE OXIDATION; THIAZOLIUM ION; ELECTRON-TRANSFER; CATIONIC MICELLE; COENZYME MODELS; FLAVIN ANALOG; ESTERIFICATION; BISCOENZYME; electron transfer; flavins; homogeneous catalysis; oxidation; photocatalysis
Dewey Decimal Classification:500 Science > 540 Chemistry & allied sciences
Status:Published
Refereed:Yes, this version has been refereed
Created at the University of Regensburg:Yes
Item ID:38597
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