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Triamidoamine thorium-arsenic complexes with parent arsenide, arsinidiide and arsenido structural motifs

Wildman, Elizabeth P. ; Balázs, Gábor ; Wooles, Ashley J. ; Scheer, Manfred ; Liddle, Stephen T.



Abstract

Despite a major expansion of uranium-ligand multiple bond chemistry in recent years, analogous complexes involving other actinides (An) remain scarce. For thorium, under ambient conditions only a few multiple bonds to carbon, nitrogen, phosphorus and chalcogenides are reported, and none to arsenic are known; indeed only two complexes with thorium-arsenic single bonds have been structurally ...

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