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Triamidoamine thorium-arsenic complexes with parent arsenide, arsinidiide and arsenido structural motifs

Wildman, Elizabeth P., Balázs, Gábor, Wooles, Ashley J. , Scheer, Manfred and Liddle, Stephen T. (2017) Triamidoamine thorium-arsenic complexes with parent arsenide, arsinidiide and arsenido structural motifs. Nature Communications 8, p. 14769.

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Other URL: http://doi.org/10.1038/ncomms14769

Dieser Artikel ist in einer Zeitschrift aus dem Directory of Open Access (DOAJ) publiziert.


Abstract

Despite a major expansion of uranium-ligand multiple bond chemistry in recent years, analogous complexes involving other actinides (An) remain scarce. For thorium, under ambient conditions only a few multiple bonds to carbon, nitrogen, phosphorus and chalcogenides are reported, and none to arsenic are known; indeed only two complexes with thorium-arsenic single bonds have been structurally ...

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Item type:Article
Date:2017
Institutions:Chemistry and Pharmacy > Institut für Anorganische Chemie > Chair Prof. Dr. Manfred Scheer
Identification Number:
ValueType
10.1038/ncomms14769DOI
Keywords:MULTIPLE BONDS; MOLECULAR-COMPOUNDS; CRYSTAL-STRUCTURES; CARBENE COMPLEXES; KETIMIDE COMPLEX; INFRARED-SPECTRA; LIGAND; REACTIVITY; PHOSPHORUS; URANIUM;
Dewey Decimal Classification:500 Science > 540 Chemistry & allied sciences
Status:Published
Refereed:Yes, this version has been refereed
Created at the University of Regensburg:Yes
Item ID:38608
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