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Element allotropes and polyanion compounds of pnicogenes and chalcogenes: stability, mechanisms of formation, controlled synthesis and characterization

Schöneich, Michael ; Hohmann, Andrea ; Schmidt, Peer ; Pielnhofer, Florian ; Bachhuber, Frederik ; Weihrich, Richard ; Osters, Oliver ; Köpf, Marianne ; Nilges, Tom


The application of the EnPhaSyn (theoretical Energy diagrams, experimental Phase formation, Syn-thesis and characterisation) concept is reviewed with respect to prediction of structures and stability of ele-ment allotropes and compound polymorphs, their phase formation and transition processes, and their directed synthesis, respectively. Therein, the relative energeti-cal stability (En) of target ...


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