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Protective Coatings for Aluminum Alloy Based on Hyperbranched 1,4-Polytriazoles

Armelin, Elaine ; Whelan, Rory ; Martínez-Triana, Yeimy Mabel ; Alemán, Carlos ; Finn, M. G. ; Díaz, David Díaz



Abstract

Organic polymers are widely used as coatings and adhesives to metal surfaces, but aluminum is among the most difficult substrates because of rapid oxidative passivation of its surface. Poly(1,4-disubstituted 1,2,3-triazoles) made by copper catalyzed azide-alkyne cycloaddition form strongly bonded interfaces with several metal substrates. In this work, a variety of alkyne and azide monomers were ...

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