Seitz, A. E., Heinl, V., Timoshkin, A. Y. 
and Scheer, M.
(2017)
Transformation of nortricyclane type cage compounds P4S3, P4Se3 and As4S3 by [Cp′′2Zr(CO)2].
Chemical Communications 53 (6), pp. 1172-1175.
Full text not available from this repository.
Other URL: http://doi.org/10.1039/c6cc09427a
Abstract
The complex [Cp"Zr-2(CO)(2)] (Cp" = C(5)H(3)tBu(2)) was used to transform the nortricyclane type cage compounds E(4)Q(3) (E = P, Q = S, Se; E = As, Q = S) resulting in unprecedented complexes [(Cp"Zr-2)(2)(mu,eta(1:1:1:1)-E(2)Q(4))] possessing bridging ligands that represent the anions of the so far unknown tetrachalcogenohypodiphosphorous acid (HQ)(2)PP(QH)(2) and tetrathiohypodiarsenous acid (HS)(2)AsAs(SH)(2), respectively.
Export bibliographical data
| Item type: | Article | ||||
|---|---|---|---|---|---|
| Date: | 2017 | ||||
| Institutions: | Chemistry and Pharmacy > Institut für Anorganische Chemie > Chair Prof. Dr. Manfred Scheer | ||||
| Identification Number: |
| ||||
| Keywords: | TRANSITION-METAL-COMPLEXES; PHOSPHORUS BOND-CLEAVAGE; RAY CRYSTAL-STRUCTURE; MAIN-GROUP ELEMENTS; DIPHOSPHORUS-SULFUR; COBALT COMPLEXES; P-4 ACTIVATION; CYCLIC UNITS; LIGANDS; CHEMISTRY; | ||||
| Dewey Decimal Classification: | 500 Science > 540 Chemistry & allied sciences | ||||
| Status: | Published | ||||
| Refereed: | Yes, this version has been refereed | ||||
| Created at the University of Regensburg: | Yes | ||||
| Item ID: | 38804 |
Altmetric
Altmetric