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Transformation of nortricyclane type cage compounds P4S3, P4Se3 and As4S3 by [Cp′′2Zr(CO)2]

Seitz, A. E., Heinl, V., Timoshkin, A. Y. and Scheer, M. (2017) Transformation of nortricyclane type cage compounds P4S3, P4Se3 and As4S3 by [Cp′′2Zr(CO)2]. Chemical Communications 53 (6), pp. 1172-1175.

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Other URL: http://doi.org/10.1039/c6cc09427a


Abstract

The complex [Cp"Zr-2(CO)(2)] (Cp" = C(5)H(3)tBu(2)) was used to transform the nortricyclane type cage compounds E(4)Q(3) (E = P, Q = S, Se; E = As, Q = S) resulting in unprecedented complexes [(Cp"Zr-2)(2)(mu,eta(1:1:1:1)-E(2)Q(4))] possessing bridging ligands that represent the anions of the so far unknown tetrachalcogenohypodiphosphorous acid (HQ)(2)PP(QH)(2) and tetrathiohypodiarsenous acid (HS)(2)AsAs(SH)(2), respectively.


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Item type:Article
Date:2017
Institutions:Chemistry and Pharmacy > Institut für Anorganische Chemie > Chair Prof. Dr. Manfred Scheer
Identification Number:
ValueType
10.1039/c6cc09427aDOI
Keywords:TRANSITION-METAL-COMPLEXES; PHOSPHORUS BOND-CLEAVAGE; RAY CRYSTAL-STRUCTURE; MAIN-GROUP ELEMENTS; DIPHOSPHORUS-SULFUR; COBALT COMPLEXES; P-4 ACTIVATION; CYCLIC UNITS; LIGANDS; CHEMISTRY;
Dewey Decimal Classification:500 Science > 540 Chemistry & allied sciences
Status:Published
Refereed:Yes, this version has been refereed
Created at the University of Regensburg:Yes
Item ID:38804
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