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Terminal Parent Phosphanide and Phosphinidene Complexes of Zirconium(IV)

Stafford, Hannah ; Rookes, Thomas M. ; Wildman, Elizabeth P. ; Balázs, Gábor ; Wooles, Ashley J. ; Scheer, Manfred ; Liddle, Stephen T.


The reaction of [Zr(Tren(DMBS))(Cl)] [Zr1; Tren(DMBS) = N(CH2CH2NSiMe2But)(3)] with NaPH2 gave the terminal parent phosphanide complex [Zr(Tren(DMBS))(PH2)] [Zr2; Zr P = 2.690(2) angstrom]. Treatment of Zr2 with one equivalent of KCH2C6H5 and two equivalents of benzo-15-crown-5 ether (B15C5) afforded an unprecedented example (outside of matrix isolation) of a structurally authenticated ...


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