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Terminal Parent Phosphanide and Phosphinidene Complexes of Zirconium(IV)

Stafford, Hannah, Rookes, Thomas M. , Wildman, Elizabeth P., Balázs, Gábor, Wooles, Ashley J. , Scheer, Manfred and Liddle, Stephen T. (2017) Terminal Parent Phosphanide and Phosphinidene Complexes of Zirconium(IV). Angewandte Chemie International Edition 56 (26), pp. 7669-7673.

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Other URL: http://doi.org/10.1002/anie.201703870


Abstract

The reaction of [Zr(Tren(DMBS))(Cl)] [Zr1; Tren(DMBS) = N(CH2CH2NSiMe2But)(3)] with NaPH2 gave the terminal parent phosphanide complex [Zr(Tren(DMBS))(PH2)] [Zr2; Zr P = 2.690(2) angstrom]. Treatment of Zr2 with one equivalent of KCH2C6H5 and two equivalents of benzo-15-crown-5 ether (B15C5) afforded an unprecedented example (outside of matrix isolation) of a structurally authenticated ...

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Item type:Article
Date:2017
Institutions:Chemistry and Pharmacy > Institut für Anorganische Chemie > Chair Prof. Dr. Manfred Scheer
Identification Number:
ValueType
10.1002/anie.201703870DOI
Keywords:COORDINATE PHOSPHORUS ATOMS; BOND-FORMING REACTIONS; CARBENE-LIKE CHEMISTRY; P MULTIPLE BOND; TRIAMIDOAMINE COMPLEXES; TUNGSTEN COMPLEXES; TITANIUM COMPLEXES; OXO COMPLEX; U-IV=C; REACTIVITY; agostic-type interactions; phosphanides; phosphinidenes; X-ray crystallography; zirconium
Dewey Decimal Classification:500 Science > 540 Chemistry & allied sciences
Status:Published
Refereed:Yes, this version has been refereed
Created at the University of Regensburg:Yes
Item ID:38883
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