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Rearrangement of a P4 Butterfly Complex-The Formation of a Homoleptic Phosphorus-Iron Sandwich Complex

Müller, Julian, Heinl, Sebastian, Schwarzmaier, Christoph, Balázs, Gábor, Keilwerth, Martin, Meyer, Karsten and Scheer, Manfred (2017) Rearrangement of a P4 Butterfly Complex-The Formation of a Homoleptic Phosphorus-Iron Sandwich Complex. Angewandte Chemie International Edition 56 (25), pp. 7312-7317.

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Other URL: http://doi.org/10.1002/anie.201703175


Abstract

The versatile coordination behavior of the P-4 butterfly complex [{Cp'" Fe(CO)(2)}(2)(mu,eta(1:1)-P-4)] (1, Cp'''=eta(5)-C(5)H(2)tBu(3)) towards different iron(II) compounds is presented. The reaction of 1 with [FeBr2 center dot dme] (dme = dimethoxyethane) leads to the chelate complex [{Cp''' Fe(CO)(2)}(2)(mu(3), eta(1:1:2)-P-4){FeBr2}] (2), whereas, in the reaction with [Fe(CH3CN)(6)][PF6](2), ...

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Item type:Article
Date:2017
Institutions:Chemistry and Pharmacy > Institut für Anorganische Chemie > Chair Prof. Dr. Manfred Scheer
Identification Number:
ValueType
10.1002/anie.201703175DOI
Keywords:TRANSITION-METAL-COMPLEXES; ELECTRON-DONATING ABILITY; P BOND; ACTIVATION; LIGANDS; FUNCTIONALIZATION; REACTIVITY; MOLECULES; CATALYSTS; ELEMENTS; cyclo-P-4 ligands; iron; P-4 butterfly complexes; P-4 transformation; phosphorus
Dewey Decimal Classification:500 Science > 540 Chemistry & allied sciences
Status:Published
Refereed:Yes, this version has been refereed
Created at the University of Regensburg:Yes
Item ID:38894
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