Go to content
UR Home

Rearrangement of a P4 Butterfly Complex-The Formation of a Homoleptic Phosphorus-Iron Sandwich Complex

Müller, Julian ; Heinl, Sebastian ; Schwarzmaier, Christoph ; Balázs, Gábor ; Keilwerth, Martin ; Meyer, Karsten ; Scheer, Manfred



Abstract

The versatile coordination behavior of the P-4 butterfly complex [{Cp'" Fe(CO)(2)}(2)(mu,eta(1:1)-P-4)] (1, Cp'''=eta(5)-C(5)H(2)tBu(3)) towards different iron(II) compounds is presented. The reaction of 1 with [FeBr2 center dot dme] (dme = dimethoxyethane) leads to the chelate complex [{Cp''' Fe(CO)(2)}(2)(mu(3), eta(1:1:2)-P-4){FeBr2}] (2), whereas, in the reaction with [Fe(CH3CN)(6)][PF6](2), ...

plus


Owner only: item control page
  1. Homepage UR

University Library

Publication Server

Contact:

Publishing: oa@ur.de
0941 943 -4239 or -69394

Dissertations: dissertationen@ur.de
0941 943 -3904

Research data: daten@ur.de
0941 943 -5707

Contact persons