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Rearrangement of a P4 Butterfly Complex-The Formation of a Homoleptic Phosphorus-Iron Sandwich Complex

Müller, Julian ; Heinl, Sebastian ; Schwarzmaier, Christoph ; Balázs, Gábor ; Keilwerth, Martin ; Meyer, Karsten ; Scheer, Manfred


The versatile coordination behavior of the P-4 butterfly complex [{Cp'" Fe(CO)(2)}(2)(mu,eta(1:1)-P-4)] (1, Cp'''=eta(5)-C(5)H(2)tBu(3)) towards different iron(II) compounds is presented. The reaction of 1 with [FeBr2 center dot dme] (dme = dimethoxyethane) leads to the chelate complex [{Cp''' Fe(CO)(2)}(2)(mu(3), eta(1:1:2)-P-4){FeBr2}] (2), whereas, in the reaction with [Fe(CH3CN)(6)][PF6](2), ...


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