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N-Heterocyclic carbene-stabilised arsinidene (AsH)

Doddi, Adinarayana ; Weinhart, Michael ; Hinz, Alexander ; Bockfeld, Dirk ; Goicoechea, Jose M. ; Scheer, Manfred ; Tamm, Matthias


N-Heterocyclic carbene adducts of the parent arsinidene (AsH) were prepared by two different synthetic routes, either by reaction of As(SiMe3)(3) with 2,2-difluoroimidazolines followed by desilylation or by reaction of [Na(dioxane)(3.31)][AsCO] with imidazolium chlorides.

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