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N-Heterocyclic carbene-stabilised arsinidene (AsH)

Doddi, Adinarayana, Weinhart, Michael, Hinz, Alexander , Bockfeld, Dirk , Goicoechea, Jose M., Scheer, Manfred and Tamm, Matthias (2017) N-Heterocyclic carbene-stabilised arsinidene (AsH). Chemical Communications 53 (45), pp. 6069-6072.

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Other URL: http://doi.org/10.1039/c7cc02628e


Abstract

N-Heterocyclic carbene adducts of the parent arsinidene (AsH) were prepared by two different synthetic routes, either by reaction of As(SiMe3)(3) with 2,2-difluoroimidazolines followed by desilylation or by reaction of [Na(dioxane)(3.31)][AsCO] with imidazolium chlorides.


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Item type:Article
Date:2017
Institutions:Chemistry and Pharmacy > Institut für Anorganische Chemie > Chair Prof. Dr. Manfred Scheer
Identification Number:
ValueType
10.1039/c7cc02628eDOI
Keywords:MAIN-GROUP ELEMENTS; MULTIPLE BONDS; INDUCED DEGRADATION; TRANSITION-METALS; COMPLEXES; PHOSPHINIDENE; ARSAALKENES; PHOSPHAALKENES; PENTACARBONYL; DERIVATIVES;
Dewey Decimal Classification:500 Science > 540 Chemistry & allied sciences
Status:Published
Refereed:Yes, this version has been refereed
Created at the University of Regensburg:Yes
Item ID:38897
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