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Mo2 B4 O9 -Connecting Borate and Metal-Cluster Chemistry

Schmitt, Martin K., Janka, Oliver, Pöttgen, Rainer, Benndorf, Christopher, de Oliveira, Marcos, Eckert, Hellmut, Pielnhofer, Florian, Tragl, Amadeus-Samuel, Weihrich, Richard, Joachim, Bastian , Johrendt, Dirk and Huppertz, Hubert (2017) Mo2 B4 O9 -Connecting Borate and Metal-Cluster Chemistry. Angewandte Chemie International Edition 56 (23), pp. 6449-6453.

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Other URL: http://doi.org/10.1002/anie.201701891


We report on the first thoroughly characterized molybdenum borate, which was synthesized in a high-pressure/high-temperature experiment at 12.3 GPa/1300 degrees C using a Walker-type multianvil apparatus. Mo2B4O9 incorporates tetrahedral molybdenum clusters into an anionic borate crystal structure-a structural motif that has never been observed before in the wide field of borate crystal ...


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Item type:Article
Institutions:Chemistry and Pharmacy > Institut für Anorganische Chemie
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Keywords:SHARING BO4 TETRAHEDRA; PLANE-WAVE; PRESSURE; SOLIDS; borates; high-pressure chemistry; molybdenum; solid-state structures; transition-metal clusters
Dewey Decimal Classification:500 Science > 540 Chemistry & allied sciences
Refereed:Yes, this version has been refereed
Created at the University of Regensburg:Yes
Item ID:38962
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