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Different Reactivity of As4 towards Disilenes and Silylenes

Seitz, Andreas E., Eckhardt, Maria, Sen, Sakya S., Erlebach, Andreas , Peresypkina, Eugenia V., Roesky, Herbert W., Sierka, Marek and Scheer, Manfred (2017) Different Reactivity of As4 towards Disilenes and Silylenes. Angewandte Chemie International Edition 56 (23), pp. 6655-6659.

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Other URL: http://doi.org/10.1002/anie.201701740


Abstract

The activation of yellow arsenic is possible with the silylene [ePhC(NtBu)(2)SiN(SiMe3)(2)] (1) and the disilene [(Me3Si)(2)N(eta(1)-Me5C5)Si=Si(eta(1)-Me5C5)N(SiMe3)(2)] (3). The reaction of As-4 with 1 leads to the unprecedented As-10 cage compound [(LSiN(SiMe3)(2))(3)As-10] (2; L - PhC(NtBu)(2)) with an As-7 nortricyclane core stabilized by arsasilene moieties containing silicon(II) ...

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Item type:Article
Date:2017
Institutions:Chemistry and Pharmacy > Institut für Anorganische Chemie > Chair Prof. Dr. Manfred Scheer
Identification Number:
ValueType
10.1002/anie.201701740DOI
Keywords:WHITE PHOSPHORUS; P-4 ACTIVATION; CAGE COMPOUNDS; COMPLEXES; DINITROGEN; ELEMENTS; BOND; TRANSFORMATION; AGGREGATION; TETRAHEDRON; arsenic; density functional calculations; silicon; silylene; small-molecule activation
Dewey Decimal Classification:500 Science > 540 Chemistry & allied sciences
Status:Published
Refereed:Yes, this version has been refereed
Created at the University of Regensburg:Yes
Item ID:38963
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