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Aromatic ionene topology and counterion-tuned gelation of acidic aqueous solutions

Bachl, Jürgen ; Bertran, Oscar ; Mayr, Judith ; Alemán, Carlos ; Díaz Díaz, David



Abstract

Unusual gelation of acidic solutions was achieved using polycations bearing quaternary ammonium moieties. These ionene polymers are based on a disubstituted phenylene dibenzamide core, which allows the construction of different topomers (i.e. ortho-1, meta-2 and para-3). The topology of the polymers was found to play a key role on their aggregation behaviour both in pure water and in a variety of ...

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