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Comment on “Conformational analysis of triphenylphosphine ligands in stereogenic monometallic complexes: tools for predicting the preferred configuration of the triphenylphosphine rotor” by J. F. Costello, S. G. Davies, E. T. F. Gould and J. E. Thomson, Dalton Trans., 2015, 44, 5451

Brunner, Henri and Tsuno, Takashi (2017) Comment on “Conformational analysis of triphenylphosphine ligands in stereogenic monometallic complexes: tools for predicting the preferred configuration of the triphenylphosphine rotor” by J. F. Costello, S. G. Davies, E. T. F. Gould and J. E. Thomson, Dalton Trans., 2015, 44, 5451. Dalton Transactions 46 (15), pp. 5103-5109.

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Other URL: http://doi.org/10.1039/c7dt00474e


Abstract

In half-sandwich compounds of the type [Cp*(MLLPPh3)-L-1-P-2] the PPh3 propeller is stabilized by attractive CH/pi interactions in which C-o-H bonds specifically interact with the C-i and C-o atoms of neighbouring phenyl rings, as in the T-shaped benzene dimer (i/o = ipso/ortho). This stabilization was not taken into account in a recent conformational analysis based on van der Waals energy ...

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Item type:Article
Date:2017
Institutions:Chemistry and Pharmacy > Institut für Anorganische Chemie
Identification Number:
ValueType
10.1039/c7dt00474eDOI
Keywords:SIXFOLD PHENYL EMBRACES; CRYSTAL SUPRAMOLECULARITY; CH/PI INTERACTIONS; PPH3; VAN; ATTRACTION; MOTIFS; RADII;
Dewey Decimal Classification:500 Science > 540 Chemistry & allied sciences
Status:Published
Refereed:Yes, this version has been refereed
Created at the University of Regensburg:Yes
Item ID:39082
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