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Improving ruthenium-based ECL through nonionic surfactants and tertiary amines

Kirschbaum-Harriman, Stefanie ; Duerkop, Axel ; Baeumner, Antje J.


The influence of surfactants and coreactants on Ru(bpy)(3)(2+) electrogenerated chemiluminescence (ECL) was investigated comparatively. Specifically, the influence that the two tertiary amines, N-butyldiethanolamine (NBEA) and 2-(dibutylamino) ethanol (DBAE) have on the ECL reaction, alone and in the presence of the two surfactants Triton T X-100 and Zonyl (R) FSN, was investigated, in comparison ...


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