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Kinetics of the SN1 Dissociation of Ligands L (Nitriles, Phosphines) in the Complexes [CpFe(P-P)L]PF6 with Variable Chelate Ring Size. A Surprising Bimolecular Substitution in the Nonchelate Complex [CpFe(PPh2Me)2L]PF6

Brunner, Henri, Kitamura, Hikaru and Tsuno, Takashi (2017) Kinetics of the SN1 Dissociation of Ligands L (Nitriles, Phosphines) in the Complexes [CpFe(P-P)L]PF6 with Variable Chelate Ring Size. A Surprising Bimolecular Substitution in the Nonchelate Complex [CpFe(PPh2Me)2L]PF6. Organometallics 36 (13), pp. 2424-2436.

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Other URL: http://doi.org/10.1021/acs.organomet.7b00311


Abstract

The complexes [CpFe{Ph2P(CH2)(n)PPh2}NCMe]-PF6, [CpFe(PPh2Me)(2)NCMe]PF6, and [CpFe{Ph2P(CH2)(n)PPh2}-PPh2(OR)PF6, R = Me, Et, and iPr, with chelate ring sizes between 4 and 7 were synthesized and characterized by spectroscopy and Xray analysis. In these complexes, the monodentate ligands acetonitrile and PPh2(OR) tend to dissociate. The kinetics of the ligand exchanges MeCN/P(OMe)(3) and ...

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Item type:Article
Date:2017
Institutions:Chemistry and Pharmacy > Institut für Anorganische Chemie
Chemistry and Pharmacy > Institut für Anorganische Chemie > Alumni or Retired Professors > Prof. Dr. Henri Brunner
Identification Number:
ValueType
10.1021/acs.organomet.7b00311DOI
Keywords:CHIRAL-AT-METAL; CRYSTAL-STRUCTURES; IRON COMPLEXES; ARENE CATIONS; ACETONITRILE; REACTIVITY; CHEMISTRY; EXCHANGE; ATOMS;
Dewey Decimal Classification:500 Science > 540 Chemistry & allied sciences
Status:Published
Refereed:Yes, this version has been refereed
Created at the University of Regensburg:Yes
Item ID:39371
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