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Strategies for the Construction of Supramolecular Dimers versus Homoleptic 1D Coordination Polymers Starting from the Diphosphorus [Cp2 Mo2 (CO)4 (η2 -P2 )] Complex and Silver(I) Salts

Elsayed Moussa, Mehdi, Fleischmann, Martin, Peresypkina, Eugenia V., Dütsch, Luis, Seidl, Michael, Balázs, Gabor and Scheer, Manfred (2017) Strategies for the Construction of Supramolecular Dimers versus Homoleptic 1D Coordination Polymers Starting from the Diphosphorus [Cp2 Mo2 (CO)4 (η2 -P2 )] Complex and Silver(I) Salts. European Journal of Inorganic Chemistry 2017 (25), pp. 3222-3226.

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Other URL: http://doi.org/10.1002/ejic.201700646


Abstract

The reactions of the tetrahedral diphosphorus [Cp2Mo2(CO)(4)(eta(2)-P-2)] (1; Cp = C5H5) complex with Ag[Al{OC(CF3)(3)}(4)] (AgTEF) (A) and Ag[FAl{OC(C6F5)(C6F10)}(3)] (AgFAl) (B) were studied. The first reaction led to the formation of the [Ag-2(eta(2)-1)(2)(eta(1):eta(1)-1)(2)][TEF](2) (2) dimer and the [Ag-2(eta(1):eta(1)-1)(3)](n)[TEF](2n) (3) coordination polymer, whereas the second reaction ...

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Item type:Article
Date:2017
Institutions:Chemistry and Pharmacy > Institut für Anorganische Chemie > Chair Prof. Dr. Manfred Scheer
Identification Number:
ValueType
10.1002/ejic.201700646DOI
Keywords:ORGANIC HYBRID MATERIALS; ONE-DIMENSIONAL POLYMERS; LIGAND COMPLEXES; NMR-SPECTROSCOPY; BUILDING-BLOCKS; PENTAPHOSPHAFERROCENE; FRAMEWORKS; CHEMISTRY; MOLECULE; BEHAVIOR; Phosphorus; Coordination polymers; Coordinating anions; Silver; Synthetic methods
Dewey Decimal Classification:500 Science > 540 Chemistry & allied sciences
Status:Published
Refereed:Yes, this version has been refereed
Created at the University of Regensburg:Yes
Item ID:39374
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