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Strategies for the Construction of Supramolecular Dimers versus Homoleptic 1D Coordination Polymers Starting from the Diphosphorus [Cp2 Mo2 (CO)4 (η2 -P2 )] Complex and Silver(I) Salts

Elsayed Moussa, Mehdi ; Fleischmann, Martin ; Peresypkina, Eugenia V. ; Dütsch, Luis ; Seidl, Michael ; Balázs, Gabor ; Scheer, Manfred


The reactions of the tetrahedral diphosphorus [Cp2Mo2(CO)(4)(eta(2)-P-2)] (1; Cp = C5H5) complex with Ag[Al{OC(CF3)(3)}(4)] (AgTEF) (A) and Ag[FAl{OC(C6F5)(C6F10)}(3)] (AgFAl) (B) were studied. The first reaction led to the formation of the [Ag-2(eta(2)-1)(2)(eta(1):eta(1)-1)(2)][TEF](2) (2) dimer and the [Ag-2(eta(1):eta(1)-1)(3)](n)[TEF](2n) (3) coordination polymer, whereas the second reaction ...


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