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Intraligand fluorescence of Zn(II) and Pt(II) complexes of pyridoxal thiosemicarbazone

Vogler, Arnd (2017) Intraligand fluorescence of Zn(II) and Pt(II) complexes of pyridoxal thiosemicarbazone. Inorganic Chemistry Communications 86, pp. 105-107.

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Other URL: http://doi.org/10.1016/j.inoche.2017.09.025


Abstract

Pyridoxal (vitamin B-6 aldehyde) thiosemicarbazone (B6TSC) is deprotonated to its anion (B6TSC - H+) in basic solution at pH = 9. It shows an intense green fluorescence with lambda(max) = 500 nm and a quantum yield of unity. Zn(II)(B6TSC - H+)(acetate) displays an blue-green intraligand (B6TSC) fluorescence of moderate intensity. The complex cation [Pt(II)(B6TSC)Cl](+) is isolated as ...

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Item type:Article
Date:2017
Institutions:Chemistry and Pharmacy > Institut für Anorganische Chemie
Chemistry and Pharmacy > Institut für Anorganische Chemie > Alumni or Retired Professors > Prof. Dr. Arnd Vogler
Identification Number:
ValueType
10.1016/j.inoche.2017.09.025DOI
Keywords:METAL-COMPLEXES; SPECTROSCOPIC PROPERTIES; LUMINESCENCE; Fluorescence; Pyridoxal thiosemicarbazone; Zinc(II); Platinum(II)
Dewey Decimal Classification:500 Science > 540 Chemistry & allied sciences
Status:Published
Refereed:Yes, this version has been refereed
Created at the University of Regensburg:Yes
Item ID:39487
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