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Synthesis and Molecular Structures of [Rh(η5 -C5 H5 )(coe)2 ] (coe = cis -cyclooctene) and [Rh(η5 -C5 H5 )(cod)] (cod = cis ,cis -η4 -1,5-cyclooctadiene)

Graf, Marion, Böttcher, Hans-Christian, Mayer, Peter and Scheer, Manfred (2017) Synthesis and Molecular Structures of [Rh(η5 -C5 H5 )(coe)2 ] (coe = cis -cyclooctene) and [Rh(η5 -C5 H5 )(cod)] (cod = cis ,cis -η4 -1,5-cyclooctadiene). Zeitschrift für anorganische und allgemeine Chemie 643 (21), pp. 1323-1325.

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Other URL: http://doi.org/10.1002/zaac.201700150


The synthesis and structural characterization of the new olefinic complex [Rh(eta(5)-C5H5)(coe)(2)] (2) (coe = cis-cyclooctene) is reported. The title compound could easily be prepared in good yield by reaction of [{Rh(mu-Cl)(coe)(2)}(2)] (1) with an appropriate amount of thallium cyclopentadienide in THF at room temperature. Single crystals of 2 were grown from n-hexane and were analyzed by ...


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Item type:Article
Institutions:Chemistry and Pharmacy > Institut für Anorganische Chemie > Chair Prof. Dr. Manfred Scheer
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Keywords:COMPLEXES; RHODIUM; EXCHANGE; Cyclopentadienyl complex; Olefin complex; Crystal structure; Rhodium
Dewey Decimal Classification:500 Science > 540 Chemistry & allied sciences
Refereed:Yes, this version has been refereed
Created at the University of Regensburg:Yes
Item ID:39561
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