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Coordination of Boron-centered Lewis Acids by organo -substituted Phosphanylboranes

Marquardt, Christian ; Kahoun, Tobias ; Baumann, Josef ; Timoshkin, Alexey Y. ; Scheer, Manfred



Abstract

The reactions of the monomeric phosphanylboranes Ph2P-BH2 center dot NMe3 (1a) and tBuHP-BH2 center dot NMe3 (1b) with the main group Lewis acids BH3 and BBr3 yield the adducts H3B center dot Ph2PBH2 center dot NMe3 (2a) and H3B center dot tBuHP-BH2 center dot NMe3 (2b), Br3B center dot Ph2PBH2 center dot NMe3 (3a), and Br3B center dot tBuHP-BH2 center dot NMe3 (3b). All these compounds were ...

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