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Coordination of Boron-centered Lewis Acids by organo -substituted Phosphanylboranes

Marquardt, Christian, Kahoun, Tobias, Baumann, Josef, Timoshkin, Alexey Y. and Scheer, Manfred (2017) Coordination of Boron-centered Lewis Acids by organo -substituted Phosphanylboranes. Zeitschrift für anorganische und allgemeine Chemie 643 (21), pp. 1326-1330.

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Other URL: http://doi.org/10.1002/zaac.201700219


Abstract

The reactions of the monomeric phosphanylboranes Ph2P-BH2 center dot NMe3 (1a) and tBuHP-BH2 center dot NMe3 (1b) with the main group Lewis acids BH3 and BBr3 yield the adducts H3B center dot Ph2PBH2 center dot NMe3 (2a) and H3B center dot tBuHP-BH2 center dot NMe3 (2b), Br3B center dot Ph2PBH2 center dot NMe3 (3a), and Br3B center dot tBuHP-BH2 center dot NMe3 (3b). All these compounds were ...

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Item type:Article
Date:2017
Institutions:Chemistry and Pharmacy > Institut für Anorganische Chemie > Chair Prof. Dr. Manfred Scheer
Identification Number:
ValueType
10.1002/zaac.201700219DOI
Keywords:PHOSPHINE-BORANE ADDUCTS; CONVENIENT ROUTE; PHOSPHORUS; BONDS; PHOSPHINOBORANES; POLYMERS; EXCHANGE; ELEMENTS; DENSITY; CHAINS; Phosphanylboranes; Phosphorus; Boron; Lewis acids; Adduct
Dewey Decimal Classification:500 Science > 540 Chemistry & allied sciences
Status:Published
Refereed:Yes, this version has been refereed
Created at the University of Regensburg:Yes
Item ID:39562
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