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Transfer Reagent for Bonding Isomers of Iron Complexes

Schmidt, Monika ; Seitz, Andreas E. ; Eckhardt, Maria ; Balázs, Gábor ; Peresypkina, Eugenia V. ; Virovets, Alexander V. ; Riedlberger, Felix ; Bodensteiner, Michael ; Zolnhofer, Eva M. ; Meyer, Karsten ; Scheer, Manfred



Abstract

The cothermolysis of As-4 and [Cp"Zr-2-(CO)(2)] (Cp" = eta(5)-C(5)H(3)tBu(2)) results in the formation of [Cp"Zr-2(eta(1:1)-As-4)] (1) in high yields and the arsenic-rich complex [(Cp"Zr-2)(Cp"Zr)(mu,eta(2:2:1)-As-5)] (2) as a minor product. In contrast to yellow arsenic, 1 is a light-stable, weighable and storable arsenic source for subsequent reactions. The transfer reaction of 1 with ...

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