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Transfer Reagent for Bonding Isomers of Iron Complexes

Schmidt, Monika, Seitz, Andreas E., Eckhardt, Maria, Balázs, Gábor, Peresypkina, Eugenia V., Virovets, Alexander V. , Riedlberger, Felix, Bodensteiner, Michael, Zolnhofer, Eva M., Meyer, Karsten and Scheer, Manfred (2017) Transfer Reagent for Bonding Isomers of Iron Complexes. Journal of the American Chemical Society 139 (40), pp. 13981-13984.

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Other URL: http://doi.org/10.1021/jacs.7b07354


Abstract

The cothermolysis of As-4 and [Cp"Zr-2-(CO)(2)] (Cp" = eta(5)-C(5)H(3)tBu(2)) results in the formation of [Cp"Zr-2(eta(1:1)-As-4)] (1) in high yields and the arsenic-rich complex [(Cp"Zr-2)(Cp"Zr)(mu,eta(2:2:1)-As-5)] (2) as a minor product. In contrast to yellow arsenic, 1 is a light-stable, weighable and storable arsenic source for subsequent reactions. The transfer reaction of 1 with ...

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Item type:Article
Date:2017
Institutions:Chemistry and Pharmacy > Institut für Anorganische Chemie > Chair Prof. Dr. Manfred Scheer
Identification Number:
ValueType
10.1021/jacs.7b07354DOI
Keywords:TRANSITION-METAL-COMPLEXES; P-4 ACTIVATION; ELECTRON-DIFFRACTION; ZIRCONIUM COMPLEXES; LIGAND COMPLEXES; PHOSPHORUS; AS-4; ELEMENTS; REACTIVITY; DISILENES;
Dewey Decimal Classification:500 Science > 540 Chemistry & allied sciences
Status:Published
Refereed:Yes, this version has been refereed
Created at the University of Regensburg:Yes
Item ID:39674
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