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A Convenient Route to Mixed Pnictogenylboranes

Hegen, Oliver, Marquardt, Christian, Timoshkin, Alexey Y. and Scheer, Manfred (2017) A Convenient Route to Mixed Pnictogenylboranes. Angewandte Chemie International Edition 56 (41), pp. 12783-12787.

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Other URL: http://doi.org/10.1002/anie.201707436


Abstract

We report on the synthesis and characterization of mixed pnictogenylboranes. The substitution of the Lewis base SMe2 in (OC)(5)W-PH2BH2-SMe2 (2) by different pnictogenylboranes ER2BH2-LB (E=P, As, Sb) leads to the Lewis acid/base stabilized butane analogue (OC)(5)W-PH2BH2ER2BH2-LB (3a,b: E=P; R=H, SiMe3; LB=NMe3; 4a,b: E=As; R=H, SiMe3; LB=NMe3; 5: E=Sb; R=SiMe3; LB=NHCMe). All of these compounds ...

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Item type:Article
Date:2017
Institutions:Chemistry and Pharmacy > Institut für Anorganische Chemie > Chair Prof. Dr. Manfred Scheer
Identification Number:
ValueType
10.1002/anie.201707436DOI
Keywords:MOLECULAR-WEIGHT POLYAMINOBORANES; PHOSPHINE-BORANE ADDUCTS; POLYSILANE HIGH POLYMERS; AMINE-BORANES; CATALYZED DEHYDROPOLYMERIZATION; AMINOBORANE COMPLEXES; INORGANIC POLYMERS; HYDROGEN-STORAGE; CONJUGATE BASE; DEHYDROGENATION; antimony; arsenic; boron; molecular chains; phosphorus
Dewey Decimal Classification:500 Science > 540 Chemistry & allied sciences
Status:Published
Refereed:Yes, this version has been refereed
Created at the University of Regensburg:Yes
Item ID:39691
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