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Interface Dipoles of Ir(ppy)₃ on Cu(111)

Queck, Fabian ; Albrecht, Florian ; Mutombo, Pingo ; Krejčí, Ondřej ; Jelinek, Pavel ; McLean, Alastair ; Repp, Jascha


The interplay of adsorption geometry and interface dipoles of the transition-metal complex \molecule\ on Cu(111) was studied using low-temperature scanning probe microscopy and density-functional-theory calculations. We find that the orientation of the molecule's intrinsic dipole moment with respect to the surface has a strong influence to the total energy of the different configurations, where ...


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