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Photocatalytic Oxidative Iodination of Electron-Rich Arenes

Narobe, Rok ; Düsel, Simon J. S. ; Iskra, Jernej ; König, Burkhard


A visible‐light‐mediated oxidative iodination of electron‐rich arenes has been developed. 2.5 mol% of unsubstituted anthraquinone as photocatalyst were used in combination with elementary iodine, trifluoroacetic acid and oxygen as the terminal oxidant. The iodination proceeds upon irradiation in non‐ or weakly‐electron donating solvents (DCM, DCE and benzene) wherein a spectral window in strongly ...


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