Meng, Qing-Yuan 
, Schirmer, Tobias, Berger, Anna Lucia, Donabauer, Karsten and König, Burkhard
(2019)
Photocarboxylation of Benzylic C-H bonds.
Journal of the American Chemical Society 141, pp. 11393-11397.
Full text not available from this repository.
Other URL: https://doi.org/10.1021/jacs.9b05360
Abstract
The carboxylation of sp3-hybridized C-H bonds with CO2 is a challenging transformation. Herein, we report a visible-light-mediated carboxylation of benzylic C-H bonds with CO2 into 2-arylpropionic acids under metal-free conditions. Photooxidized triisopropylsilanethiol was used as the hydrogen atom transfer catalyst to afford a benzylic radical that accepts an electron from the reduced form of ...
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| Item type: | Article | ||||
|---|---|---|---|---|---|
| Date: | 2019 | ||||
| Institutions: | Chemistry and Pharmacy > Institut für Organische Chemie > Lehrstuhl Prof. Dr. Burkhard König | ||||
| Projects: | DFG KO 1537/18-1, ERC No. 741623 | ||||
| Identification Number: |
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| Keywords: | Carboxylation; visible-light; metal-free | ||||
| Dewey Decimal Classification: | 500 Science > 540 Chemistry & allied sciences | ||||
| Status: | Published | ||||
| Refereed: | Yes, this version has been refereed | ||||
| Created at the University of Regensburg: | Yes | ||||
| Item ID: | 40471 |
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