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Synthesis and Coordination Chemistry of Anionic Pnictogenylborane Derivatives

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Kahoun, Tobias
Date of publication of this fulltext: 28 Sep 2020 08:29

Abstract (English)

Reaction of the Lewis base stabilized parent phosphanylborane H2P-BH2-NMe3 (C1) with the phosphorus based nucleophile NaPH2 leads to the formation of the anionic chain like compound [Na(C12H24O6)][H2P-BH2-PH2] (C3) in the presence of 18-crown-6 (C12H24O6). The analog reaction with corresponding arsenic containing starting materials KAsH2 and H2As-BH2-NMe3 (C2) results in ...


Translation of the abstract (German)

Die Reaktion der Lewis-Base-stabilisierten Stammverbindung des Phosphanylborans H2P-BH2-NMe3 (C1) mit dem phosphorbasierten Nukleophil NaPH2 führt zur Bildung der anionischen kettenartigen Verbindung [Na(C12H24O6)][H2P-BH2-PH2] (C3) in Anwesenheit von 18-Krone-6 (C12H24O6). Die analoge Reaktion mit den entsprechenden arsenhaltigen Edukten KAsH2 und H2As-BH2-NMe3 (C2) führt zu ...


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