Metal- and Oxidant-Free Photoinduced Aromatic Trifluoromethylation Performed in Aerated Gel Media: Determining the Effects on Yield and Selectivity

URN to cite this document:: urn:nbn:de:bvb:355-epub-415610
DOI to cite this document:: 10.5283/epub.41561

Abramov, Alex

; Vernickel, Hendrik ; Saldías, César

; Diaz Diaz, David

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Date of publication of this fulltext: 12 Feb 2020 11:46

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Abstract

In this work we have investigated the potential benefits of using supramolecular gel networks as reaction media to carry out air-sensitive metal-free light-induced trifluoromethylation of six-membered (hetero)arenes under aerobic conditions. This reaction was performed at room temperature (RT) using sodium triflinate (CF3SO2Na, Langlois' reagent) as a source of radicals and diacetyl as electron ...