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Gärtner, Stefanie ; Tiefenthaler, Susanne ; Korber, Nikolaus ; Stempfhuber, Sabine ; Hischa, Birgit

Structural Chemistry of Halide Including Thallides A8Tl11X (A=K, Rb, Cs; X=Cl, Br)

Gärtner, Stefanie , Tiefenthaler, Susanne, Korber, Nikolaus , Stempfhuber, Sabine und Hischa, Birgit (2018) Structural Chemistry of Halide Including Thallides A8Tl11X (A=K, Rb, Cs; X=Cl, Br). Crystals 8, S. 319.

Veröffentlichungsdatum dieses Volltextes: 18 Feb 2020 14:02
Artikel
DOI zum Zitieren dieses Dokuments: 10.5283/epub.41639


Zusammenfassung

A(8)Tl(11) (A = alkali metal) compounds have been known since the investigations of Corbett et al. in 1995 and are still a matter of current discussions as the compound includes one extra electron referred to the charge of the Tl-11(7-) cluster. Attempts to substitute this additional electron by incorporation of a halide atom succeeded in the preparation of single crystals for the lightest triel ...

A(8)Tl(11) (A = alkali metal) compounds have been known since the investigations of Corbett et al. in 1995 and are still a matter of current discussions as the compound includes one extra electron referred to the charge of the Tl-11(7-) cluster. Attempts to substitute this additional electron by incorporation of a halide atom succeeded in the preparation of single crystals for the lightest triel homologue of the group, Cs8Ga11Cl, and powder diffraction experiments for the heavier homologues also suggested the formation of analogous compounds. However, X-Ray single crystal studies on A(8)Tl(11)X to prove this substitution and to provide a deeper insight into the influence on the thallide substructure have not yet been performed, probably due to severe absorption combined with air and moisture sensitivity for this class of compounds. Here, we present single crystal X-Ray structure analyses of the new compounds Cs8Tl11Cl0.8, Cs8Tl11Br0.9, Cs5Rb3Tl11Cl0.5, Cs5.7K2.3Tl11Cl0.6 and K4Rb4Tl11Cl0.1. It is shown that a (partial) incorporation of halide can also be indirectly determined by examination of the Tl-Tl distances, thereby the newly introduced cdd/cd(av) ratio allows to evaluate the degree of distortion of Tl-11(7-) clusters.



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Details

DokumentenartArtikel
Titel eines Journals oder einer ZeitschriftCrystals
Verlag:MDPI
Ort der Veröffentlichung:BASEL
Band:8
Seitenbereich:S. 319
Datum2018
InstitutionenChemie und Pharmazie > Institut für Anorganische Chemie > Arbeitskreis Prof. Dr. Nikolaus Korber
Chemie und Pharmazie > Zentrale Analytik
Identifikationsnummer
WertTyp
10.3390/cryst8080319DOI
Stichwörter / KeywordsSOLID-STATE; CLUSTERS; ANNOUNCEMENT; METALS; PHASES; thallide; intermetallics; single crystal; X-ray structure analysis
Dewey-Dezimal-Klassifikation500 Naturwissenschaften und Mathematik > 540 Chemie
StatusVeröffentlicht
BegutachtetJa, diese Version wurde begutachtet
An der Universität Regensburg entstandenJa
URN der UB Regensburgurn:nbn:de:bvb:355-epub-416392
Dokumenten-ID41639

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